Zinc Oxide Desulfurization Adsorbent, which is applicable to desulfurization of residue cracking gases or syngas and purification of feed gases for organic synthesis processes. It is suitable for both higher (350--408℃) and lower(150--210℃) temperature use. It can convert some simpler organic sulfur while absorbing inorganic sulfur in gas stream.
Main reaction of the desulfurization process is as follows:
(1) Reaction of zinc oxide with hydrogen sulfide
H2S+ZnO=ZnS+H2O
(2) Reaction of zinc oxide with some simpler sulfur compounds in two possible ways:
a. Organic sulfur compounds, catalyzed by zinc oxide, react with hydrogen to form hydrogen sulfide:
CS2 + 4H2 = CH4 + 2H2S
C2H5SH + H2 = C2H6 + H2S
Then hydrogen sulfide is absorbed by zinc oxide
H2S+ZnO=ZnS+H2O
b. Zinc oxide reacts directly with organic sulfur compounds
COS + ZnO = ZnS + CO2
XINTAO ZnO Catalyst is an ideal desulfurization adsorbent for deep purification cases, especially those at higher temperature (350--400℃).
Model |
Zinc oxide desulfurization adsorbent (ZnO Catalyst) |
Color |
White or light yellow |
Shape |
extrude |
Normal size(mm) |
Φ4×4--15 |
Bulk Density(kg/L) |
1.0-1.3 |
Crushing strength(N/cm) |
≥50 |
Loss on Attrition(%) |
≤6 |
Breakthrough sulfur capacity, wt% |
≥28(350℃) |
Pressure, MPa |
ambient to 4.0 |
Temperature ℃ |
180-400 |
Space velocity, h-1 |
1000-2000(gas) |
Sulfur in feed gas, mg/m3 |
1-20 (≤200℃) |
Sulfur in treated stream, ppm |
max0.1 |
Loading |
Loading depth: Higher L/D (min3) is recommended. Configuration of two reactors in series can improve utilization efficiency of the adsorbent. |
Start-up |
(1)Replace the system by nitrogen or other inert gases until oxygen concentration in the gas is less than 0.5%; |
Shut-down |
(1)Emergent shut-down |
Transportation and storage |
(1)The adsorbent product is packed in plastic super sacks or iron barrels with plastic lining to prevent moisture and chemical contamination. |
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